Flame structure of supercritical ethanol/water combustion in a co-flow air stream characterized by Raman chemical analysis

[Display omitted] •Raman characterization of hydrothermal flames.•Temperature and species profiles for co-flow laminar and weakly turbulent flames.•Images and measurements of steady hydrothermal flames in under-ventilated and over-ventilated air:fuel regimes.•Results from Raman spectroscopy provide details of flame geometry and species concentrations. The thermochemical properties of the ethanol hydrothermal flame (30%-v ethanol-water solution), established in air co-flow under supercritical water conditions, are measured by a quantitative Raman diagnostic technique. The unique spectroscopic features of the chemical compounds are revealed to aid understanding of the fuel decomposition and oxidation process in supercritical phase. A point-wise fiber-optic probe is designed to resolve the needle-like thin flame and identify the spatial profiles – across the flame thickness and over the height of the visible flame – of the combustion species at different fuel/air ratios and airflow rates. An attempt is made to analyze the steep thermal gradients in the primary reaction zone near the fuel nozzle by estimating thermodynamic temperatures from the measured fluid density. The test cell was held at conditions above the critical point of water, at a nominal pressure of 25 MPa and a nominal temperature of 723 K (450 °C). The flames were over ventilated with an excess air:fuel ratio between two and five times stoichiometric. Depending upon the air:fuel ratio non-sooting blue flames or yellow sooting flames are observed. The results of the Raman diagnostic provide temperature and species profiles that will prove useful for validating numerical models using an idealized laboratory hydrothermal flame. The Raman diagnostic results are augmented with imaging from two orthogonal camera views: a backlit shadow-graphic image of the co-flow jet and a color image of the flame.