Valorisation of mango peel: Proximate composition, supercritical fluid extraction of carotenoids, and application as an antioxidant additive for an edible oil

[Display omitted] •Chemical composition of Colombian mango peel var. Sugar was explored.•The effects of freeze-drying and air-drying on the total carotenoid content were assessed.•Ethanol concentration showed the greatest significant effect in ScCO2 optimization.•The optimal conditions to maximize t...

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Veröffentlicht in:The Journal of supercritical fluids 2019-10, Vol.152, p.104574, Article 104574
Hauptverfasser: Sánchez-Camargo, Andrea del Pilar, Gutiérrez, Luis-Felipe, Vargas, Sandra Milena, Martinez-Correa, Hugo A., Parada-Alfonso, Fabián, Narváez-Cuenca, Carlos-Eduardo
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Sprache:eng
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Zusammenfassung:[Display omitted] •Chemical composition of Colombian mango peel var. Sugar was explored.•The effects of freeze-drying and air-drying on the total carotenoid content were assessed.•Ethanol concentration showed the greatest significant effect in ScCO2 optimization.•The optimal conditions to maximize the carotenoid extraction yield was 25.0 MPa, 60 °C and 15% w/w ethanol.•ScCO2 optimum extract provides better protection to sunflower oil than all-trans-β-carotene. Mango peel (MP) is an important by-product of the industrial mango processing, rich in phytochemical compounds. This study optimized the operating parameters of the supercritical CO2 extraction (ScCO2) of carotenoids from MP by means of a Box-Behnken design. The MP was characterized in terms of its proximate composition, and the effects of freeze-drying and air-drying on its total carotenoid content were investigated. The carotenoids profile of the optimal ScCO2 extract was characterized by RP-UHPLC-DAD. This extract was evaluated as natural antioxidant for sunflower oil, using the Rancimat® method. MP displayed high contents of crude protein and phenolic compounds. Although freeze-drying prevented the degradation of all-trans-β-carotene, air-drying was selected for the valorisation strategy. The higher yields of carotenoids were found at 25.0 MPa, 60 °C, and 15% w/w ethanol. Under these conditions the MP-extracts protected the sunflower oil against lipid oxidation, which could be regarded as an interesting alternative for MP valorisation.
ISSN:0896-8446
1872-8162
DOI:10.1016/j.supflu.2019.104574