A novel super high latent heat ternary eutectic salt for high temperature thermal energy storage

This work is concerned with a novel ternary eutectic salt based phase change material (PCM) for high temperature thermal energy storage applications. We designed the PCM formulation in a FactSage environment and demonstrated that the formulation had a very high latent heat. The microstructure, thermal physical properties, thermal stability and cycling service life of the eutectic salt were measured experimentally with various analytical methods including scanning electron microscopy (SEM), X-ray diffractometer analysis (XRD), simultaneous thermogravimetric analyzer (STA) technique, differential scanning calorimeter (DSC) and thermogravimetric analysis (TGA). The results indicated that the eutectic salt had a melting point of 552.23 °C with a superhigh fusion enthalpy of 661.33 J/g. The change of melting point and latent heat of salt after 1500 cycles is 0.48% and 7.84%, respectively, showing excellent cycle stability. •A novel ternary eutectic salt Li2CO3–NaCl–LiF was designed by using a three-step method and the formulation was predicted in a FactSage environment.•The eutectic salt had a superheat of fusion of 661.33 J/g with a melting point of 552.23 °C.•The eutectic salt showed excellent thermal stability and service life after 1500 cycles.