Hybrid electrochromic device with transparent electrolyte

Hybrid electrochromic (EC) devices present an interesting configuration in which the advantage of both solid-state and liquid-based devices can be combined in order to optimize the device performances. In this configuration, a solid-state EC material is combined with a redox couple dissolved in the electrolyte. The redox electrolyte offers an unlimited charge capacity, thus allowing to fully exploit the electrochromic properties of the EC material. Here, we present a thiolate/disulphide (T−/T2) redox couple as a new redox shuttle for EC devices. In order to transfer the advantages of the redox couple to a solid state device, it was combined with a fully transparent thermally curable vinyl-acetate polymer. The obtained EC device was compared with that based on I−/I3− showing higher transparency in the visible region of the solar spectrum and higher coloration efficiency. Most interestingly, the device based on T−/T2 shows a slower self-bleaching process and it only loses 30% of its coloration after 1 h at open circuit. Such characteristic represents a great advantage for smart windows applications since it is not necessary to apply potential to maintain the device coloration, thus allowing a great energy saving. [Display omitted] •Development of transparent electrolyte based on disulfide/thiolate (T2/T−) redox couple.•Exploitation of transparent electrolyte in hybrid electrochromic device.•Electrochemical and optical characterization of redox couple and complete electrochromic device.