Constructing superhydrophilic/superhydrophobic Janus membrane assisted by dual-interface-confined strategy for on-demand oil-in-water and water-in-oil emulsions separation
A Janus membrane with asymmetric superwettability on opposite surface for efficient on-demand oil-in-water and water-in-water emulsions separation. [Display omitted] •A dual-interface-confined strategy for preparing a stable Janus membrane with asymmetric superwettability.•Featured both superhydroph...
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Veröffentlicht in: | Separation and purification technology 2024-12, Vol.350, p.127846, Article 127846 |
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Sprache: | eng |
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Zusammenfassung: | A Janus membrane with asymmetric superwettability on opposite surface for efficient on-demand oil-in-water and water-in-water emulsions separation.
[Display omitted]
•A dual-interface-confined strategy for preparing a stable Janus membrane with asymmetric superwettability.•Featured both superhydrophilicity/underwater superoleophobicity and superhydrophobic/superoleophilicity.•Achieving both water-in-oil and oil-in-water emulsions separation by simple reversing the membrane.•Promotion long-term on-demand oil/water emulsion separation without significant performance decline.
Janus membranes with asymmetric wettability have attracted much attention because they can solve the problem that a single wettable material cannot effectively separate complex oil/water emulsions. Here, a dual-interface-confined strategy combining single-side interface-confined floating and single-side interface-confined spraying methods is provided to fabricate a robust Janus membrane with superwettability. The controllable single-side interface-confined floating method introduces a superior stable hydrophobic-superhydrophilic Janus interface, and the single-side interface-confined spraying method guarantees a robust superhydrophobic-superhydrophilic Janus interface. The Janus membrane featured both superhydrophilicity and superhydrophobicity with the outstanding stable interface and remarkable chemical stability could separate not only surfactant-stabilized water-in-oil emulsions by gravity alone, but also handle the surfactant-stabilized oil-in-water emulsions under low separation pressure through simple operation process. Moreover, this superwettable Janus membrane can achieve long-term on-demand oil/water emulsion separation with low flux decline and near 100% flux recovery. Overall, this work develops a new avenue for Janus membrane and provides a new application for a variety of oily wastewater treatment problems. |
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ISSN: | 1383-5866 |
DOI: | 10.1016/j.seppur.2024.127846 |