Migration behavior of Cr(VI) during the transformation of ferrihydrite-Cr(VI) co-precipitates: The interaction between surfactants and co-precipitates

Redistribution of Cr(VI) in ferrihydrite-Cr(VI) co-precipitates (Fh-Cr) was affected by co-precipitates transformation and coexisting substances. These effects were crucial for predicting the migration path of Cr(VI) in ferrihydrite-Cr(VI) co-precipitates. This work investigated the effects of the extensively used surfactants of anionic surfactant sodium dodecylbenzene sulfonate (SDBS) and cationic surfactant cetyltrimethylammonium bromide (CTAB) on the Fh-Cr transformation and redistribution of Cr(VI) for 10 days at different pH values (5.0, 7.5 and 9.0) and concentration of surfactants (0.5, 2.0 and 5.0 mM). The results showed that SDBS hindered the transformation of Fh-Cr to hematite and tended to transform into goethite. SDBS inhibited hematite formation by inhibiting the aggregation of Fh-Cr particles, and it enhanced the dissolution of Fh-Cr to facilitate the formation of goethite. Affected by the inhibition of Fh-Cr transformation, the process of Cr(VI) redistribution was delayed. CTAB did not affect the transformation of Fh-Cr, but allowed more Cr(VI) to enter the interior of iron minerals. When the surfactants were adsorbed on the Fh-Cr, SDBS decreased the adsorption of Cr(VI) by Fh-Cr, while CTAB increased the Cr(VI) adsorption. The findings of this study contribute to understand the effects of surfactants on the transformation of Fh-Cr and the behaviors of Cr(VI) during this process. [Display omitted] •The fate of Cr(VI) in Fh-Cr during transformation was affected by surfactants.•SDBS and CTAB have different effects on the behavior of Cr(VI) in Fh-Cr during aging.•SDBS inhibited the conversion of Fh-Cr to hematite but tended to produce goethite.•CTAB has no effect on the conversion but allows more Cr(VI) into the iron minerals.•SDBS and CTAB have opposite effects on the adsorption of Cr(VI) on Fh-Cr.