One-step hydrothermal method synthesized pH-dependent carbon dots for multistage anti-counterfeiting

[Display omitted] •Color-changing fluorescent CDs with pH dependence were prepared by using cheap and environmentally friendly raw materials.•The CDs have high fluorescence intensity, good stability, long fluorescence lifetime, and high fluorescence quantum yield.•The CDs is applied to multi-stage anti-counterfeiting ink; and has high fluorescence stability while discoloration is obvious. Work to combat counterfeiting has always been crucial to defending the interests of the public. The usual anti-counterfeiting marks are now fundamental and easy to imitate. Therefore, it is more beneficial to anti-counterfeiting work to develop an anti-counterfeiting mark with more variations to make forgery more difficult. Due to its exceptional stability and fluorescence variability, carbon dots (CDs), a newly developed fluorescent material, offer a wide range of potential applications in anti-counterfeiting. However, there currently needs to be more CD applications in multi-level anti-counterfeiting, and additional issues include high cost and environmental contamination. Therefore, considering the problems of green environmental protection and cost, CDs with excellent green (530 nm) and blue (475 nm, 486 nm) luminescence properties were prepared by a one-step reaction of m-phenylenediamine and glucose. The average fluorescence lifespan is longer than 5 ns, and the optimal quantum yield can reach 37%. Due to the large number of protonated amino groups and surface carboxyl functional groups, the prepared carbon dots exhibit green and blue fluorescence emission modes under acidic and alkaline conditions, respectively. Based on this situation, we produced CD ink and successfully used it for multi-level anti-counterfeiting.