Enhanced visible light photocatalytic activity of TiO2 co-doped with Fe, Co, and S for degradation of Cango red

[Display omitted] •Three different TiO2/Fe/Co/S Photocatalyst were synthesized using sol-gel method.•XRD, SEM, EDX, FT-IR, UV–Vis reflectance spectroscopy, UV–Vis Spectroscopy techniques were used to characterize them.•Photocatalytic activity was examined for Cango Red dye.•A useful technique for de...

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Veröffentlicht in:Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Molecular and biomolecular spectroscopy, 2021-07, Vol.255, p.119644, Article 119644
Hauptverfasser: Imran, Muhammad, Saeed, Zohaib, Pervaiz, Muhammad, Mehmood, Kashif, Ejaz, Rabia, Younas, Umer, Nadeem, Hafiz Amir, Hussain, Shah
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Sprache:eng
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Zusammenfassung:[Display omitted] •Three different TiO2/Fe/Co/S Photocatalyst were synthesized using sol-gel method.•XRD, SEM, EDX, FT-IR, UV–Vis reflectance spectroscopy, UV–Vis Spectroscopy techniques were used to characterize them.•Photocatalytic activity was examined for Cango Red dye.•A useful technique for degradation of dye. The photocatalytic activity of TiO2 was enhanced under visible light when it was co-doped with Fe, Co, and S through the sol-gel method. The resultant nano photocatalysts were characterized by XRD, EDX coupled with SEM, FT-IR, UV–Vis, and UV-DRS. The concentration ratio of precursor salts of Fe and S was kept at 1% each and of Co varied between 0.5% −1.5%. The photodegradation of Congo red was carried out and various factors like the concentration of catalyst, initial concentration of dye, pH, and irradiation time were also investigated to optimize the degradation process. Under optimized degradation conditions, 99.3% of Congo red (30 ppm) was degraded at slightly acidic pH, with 0.14 g of photocatalyst within 70 min of irradiation time.
ISSN:1386-1425
DOI:10.1016/j.saa.2021.119644