Time and isotopic constraints for Early Tonian basaltic magmatism in a large igneous province of the São Francisco – Congo paleocontinent (Macaúbas basin, Southeast Brazil)

•Tonian (889 ± 10 Ma) anorogenic magmatism in the São Francisco – Congo paleocontinent.•Continental rifting with asthenospheric upwelling and mantle sourced magmatism.•Nd and Hf isotopic signatures characterize a moderately- to- juvenile rifting magmatism. The Neoproterozoic Macaúbas basin (southeast Brazil) provides key hints to unravel the history of the São Francisco – Congo paleocontinent before its amalgamation as part of Gondwana. Among the several Proterozoic taphrogenic events and anorogenic igneous episodes documented for the São Francisco – Congo paleocontinent, Early Tonian event has been particularly focused on in the literature owing to the large production of bimodal (felsic-mafic) magmas now found in the Araçuaí (SE Brazil) – West Congo (SW Africa) orogenic system (AWCO) and neighboring cratonic regions. Aiming to examine the stratigraphic relations, timing and isotopic signatures of extensive basaltic magmatism related to the Macaúbas basin, we carried out detailed field, lithochemical, isotope (whole-rock Sm-Nd and Lu-Hf in zircon) geochemistry and zircon U-Pb geochronological studies on the Pedro Lessa suite and Planalto de Minas Formation, located in the central-western Araçuaí orogen. The studied Pedro Lessa suite consists of a series of mafic dikes that crosscut the lowermost units of the Macaúbas Group but not the Planalto de Minas Formation. The Pedro Lessa suite yielded zircon U-Pb ages between 951 ± 54 Ma and 939 ± 7 Ma. The Planalto de Minas Formation comprises volcaniclastic rocks crystallized at 889 ± 10 Ma, and sedimentary rocks with maximum depositional age of 867 ± 10 Ma. The lithochemical and isotopic datasets (Pedro Lessa dikes: εNd(t) = +0.60; εHf(t) = –22.21 to +4.66; Planalto de Minas volcanism: εNd(t) = +0.76 to +0.78; εHf(t) = −19.27 to +10.03) indicate predominantly continental tholeiite and minor enriched MORB-type mantle magmas with variable amounts of crustal contamination. The (La/Sm)N ratios indicate a theoretical partial melting (1–7%) of the spinel-lherzoite lithospheric zone for the Pedro Lessa suite, and of the spinel-garnet transition zone (3–10%) for the Planalto de Minas metamafic rocks, in accordance with La/Nb and La/Ba ratios. The new and complied isotopic and lithochemical data suggest a time-dependent evolution of magma sources, with lithospheric mantle sources for the Early Tonian dike swarms (Pedro Lessa and correlatives) evolving to predominantly asthenospheric mantle sources for the late basaltic