Synthesis of PDMS/PEG graft-like and block copolymers via industrially relevant reverse iodine transfer polymerization

Advanced polymer structures are gaining traction in the coatings industry where they may, for instance, give rise to antifouling and anti-icing surfaces. With a focus on industrial feasibility, a series of copolymers from poly(dimethylsiloxane) monomethacrylate (PDMSMA), methoxy poly(ethylene glycol) monomethacrylate (MPEGMA) and methyl methacrylate (MMA) were prepared via reverse iodine transfer polymerization (RITP) and reversible complexation mediated polymerization (RCMP). Using inexpensive materials and synthesis approaches scalable for larger industrial quantities, a variety of (amphiphilic) copolymers and block copolymers were prepared. Compared to semi-batch free-radical polymerization (FRP), the RITP/RCMP approaches resulted in higher conversions of the macromonomers, lower polymer dispersities, allowed synthesis of block copolymers, as well as being simpler than most other common RDRP techniques. [Display omitted] •Graft-like PDMSMA/MPEGMA/MMA copolymers were prepared with high monomer conversion via reverse iodine transfer polymerization.•RITP utilized to prepare bottle brush type block-copolymers from iodine capped poly(PDMSMA) macro transfer agents.•Well defined bottle brush type poly(PDMSMA-b-MMA) with low dispersity (ÐM