Weakly coupled Type-II superconductivity in a breathing Kagome metal ZrRe2

We present a comprehensive investigation of the superconducting properties of ZrRe2, a Re-based hexagonal Laves compounds. ZrRe2 crystallizes in a C14-type structure (space group P63/mmc), where the Re atoms form a breathing Kagome lattice, with cell parameters a = b = 5.2682(5) Å and c = 8.63045 Å....

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Veröffentlicht in:Physica. C, Superconductivity Superconductivity, 2024-11, Vol.626, p.1354604, Article 1354604
Hauptverfasser: Yu, Yingpeng, Liu, Zhaolong, Li, Qi, Chen, Zhaoxu, Wang, Yulong, Hao, Munan, Yang, Yaling, Wang, Xuhui, Gong, Chunsheng, Chen, Long, Xie, Zhenkai, Zhou, Kaiyao, Ren, Huifen, Chen, Xu, Jin, Shifeng
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Sprache:eng
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Zusammenfassung:We present a comprehensive investigation of the superconducting properties of ZrRe2, a Re-based hexagonal Laves compounds. ZrRe2 crystallizes in a C14-type structure (space group P63/mmc), where the Re atoms form a breathing Kagome lattice, with cell parameters a = b = 5.2682(5) Å and c = 8.63045 Å. Through transport measurements, the superconducting transition is observed with Tconset = 6.44 K and Tczero = 6.06 K. In magnetization measurements(ZFC-FC) superconducting transition occurs at 6.12 K. The measured lower and upper critical fields are 6.27 mT and 7.84 T, respectively. Measurements of the specific heat capacity confirm the presence of bulk superconductivity, with a normalized specific heat change of ΔCe/γTc=1.63 and an electron-phonon strength of λep=0.69. DFT calculations revealed that the band structure of ZrRe2 is intricate and without van Hove singularity.
ISSN:0921-4534
DOI:10.1016/j.physc.2024.1354604