Boosting up color tunability of Sr2Ga2GeO7 by energy transfer between Dy3+ and Eu3+ ions

A series of Sr2Ga2GeO7 (SGGO) phosphors doped with Dy3+ and/or Eu3+ were synthesized using solid-phase reaction. The structure and luminescence properties of phosphors were studied. The XRD, FT-IR, SEM and XPS analysis show that the doping with trivalent Dy and Eu have no effect on the structure of...

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Veröffentlicht in:Optical materials 2023-05, Vol.139, p.113772, Article 113772
Hauptverfasser: Wan, Jiangyun, Wu, Haoyi, Li, Yanmei, Chen, Yonglin, Peng, Chaoyue, Chen, Geng, Hu, Yihua
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Sprache:eng
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Zusammenfassung:A series of Sr2Ga2GeO7 (SGGO) phosphors doped with Dy3+ and/or Eu3+ were synthesized using solid-phase reaction. The structure and luminescence properties of phosphors were studied. The XRD, FT-IR, SEM and XPS analysis show that the doping with trivalent Dy and Eu have no effect on the structure of the phosphor, and the feature emission of Dy3+ or Eu3+ was observed by photoluminescence investigation. Based on the spectral overlapping of the Dy3+ emission and Eu3+ excitation, there is an energy transfer from Dy3+ to Eu3+ in the Sr2Ga2GeO7. Under excitation at 344 nm, with the increment of Eu3+ concentration, the Dy3+ emission intensity was decreased and the emission lifetime was shortened, whereas the lifetime of Eu3+ was increased, confirming the energy transfer from Dy3+ to Eu3+. The resulting tunable orange emission has potential applications in plant growth. •The luminescence of Dy3+ was observed in Sr2Ga2GeO7.•The color tenability was observed via energy transfer from Dy3+ to Eu3+.•The Dy3+ to Eu3+ and Sr2Ga2GeO7 has a good thermal stability.
ISSN:0925-3467
1873-1252
DOI:10.1016/j.optmat.2023.113772