Fabrication of an electrochemical sensor based on gold nanoparticles functionalized polypyrrole nanotubes for the highly sensitive detection of l-dopa

[Display omitted] •Nanotubular form of polypyrrole has been prepared using self-degraded template.•Gold nanoparticles added polypyrrole nanotubes provide good conductivity and surface area.•AuNP/PPy/ modified GCE showed excellent electrocatalytic performance for L-dopa oxidation. Polypyrrole (PPy) n...

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Veröffentlicht in:Materials today communications 2020-12, Vol.25, p.101330, Article 101330
Hauptverfasser: Kannan, Ayyadurai, Radhakrishnan, Sivaprakasam
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Sprache:eng
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Zusammenfassung:[Display omitted] •Nanotubular form of polypyrrole has been prepared using self-degraded template.•Gold nanoparticles added polypyrrole nanotubes provide good conductivity and surface area.•AuNP/PPy/ modified GCE showed excellent electrocatalytic performance for L-dopa oxidation. Polypyrrole (PPy) nanotubes were obtained by using methyl orange and FeCl3 as self-degraded template. Subsequently, gold nanoparticles (AuPs) were deposited on the PPy nanoutbes by electrochemical method. The as-prepared PPy-AuNPs hybrid composite was studied by different physical and electrochemical characterizations. The PPy-AuNPs was coated over the glassy carbon electrode (GCE) where shows a well electrochemical activity for l-dopa detection in term of lower detection limit (0.075 μM), less oxidation potential (380 mV), good stability and reproducibility. The modified electrode was successfully utilized for detection of l-dopa in real samples.
ISSN:2352-4928
2352-4928
DOI:10.1016/j.mtcomm.2020.101330