Recyclable copper-decorated magnetic composites as non-precious catalysts for effective removal of 4-nitrophenol and azo dyes

•The wasted lotus leaf was recycled to fabricate non-noble magnetically recoverable catalysts CuX-FCLL.•The Cu1.5-FCLL catalyst exhibited an ultrafast catalytic ability and good stability for 4-nitrophenol degradation.•The unique papillae structures of the carbonized lotus leaf as support of Cu-Fe3O...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Materials science & engineering. B, Solid-state materials for advanced technology Solid-state materials for advanced technology, 2023-07, Vol.293, p.116465, Article 116465
Hauptverfasser: Huang, Xiang, Lin, Changcheng, Ding, Xiuyan, Yang, Yanting, Ge, Hongliang
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:•The wasted lotus leaf was recycled to fabricate non-noble magnetically recoverable catalysts CuX-FCLL.•The Cu1.5-FCLL catalyst exhibited an ultrafast catalytic ability and good stability for 4-nitrophenol degradation.•The unique papillae structures of the carbonized lotus leaf as support of Cu-Fe3O4 nanoparticles could provide large surface areas and prevent aggregation of metal NPs, and boost the catalytic performance of Cu1.5-FCLL by a synergetic effect.•The magnetically recoverable Cu1.5-FCLL catalyst had a universal degradation potential towards various pollutants. Carbonized lotus leaf (CLL) from agricultural waste is employed as the support to prepare the novel Cu-Fe3O4/carbonized lotus leaf (CuX-FCLL) catalysts. The magnetic catalyst Cu1.5-FCLL demonstrated desirable catalytic activity for the reduction of organic dyes (Congo red, Methyl orange) and nitroaromatic compounds (3- and 4-nitrophenols). The magnetically recoverable catalyst (Cu1.5-FCLL) exhibited ultrafast catalytic activity for 4-nitrophenol reduction with a conversion rate of over 98% within 30 s, which was comparable to those noble metal catalysts widely used. The CLL with unique papillae structures could provide large surface areas and prevent aggregation of metal NPs, and boost the catalytic performance of Cu1.5-FCLL by a synergetic effect. Such a magnetic catalyst was facilely recovered and reused after ten cycles with negligible loss of catalytic performance. This work presents an efficient green catalyst to replace noble metals for wastewater treatment.
ISSN:0921-5107
1873-4944
DOI:10.1016/j.mseb.2023.116465