Microstructure, mechanical properties, and shape memory behavior of laser-directed energy deposited Co–20Fe–18Cr–19Mn high-entropy alloy

Laser additive manufacturing has become a powerful tool in modern production processes, and the additive manufacturing of Cantor-type high-entropy alloys has attracted considerable attention owing to its unique properties. In this study, we successfully utilized a laser-directed energy deposition (L-DED) process to fabricate a Co–20Fe–18Cr–19Mn, wt.% (Co40Fe20Cr20Mn20, at.%) alloy and analyzed its microstructure, room temperature mechanical properties, and shape memory effect. Microstructural analysis revealed a dense microstructure of the alloy. Before heat treatment, the alloy exhibited a microstructure consisting of both columnar and equiaxed dendrites with a hexagonal close-packed structure (HCP). However, post-treatment led to a completely different microstructure owing to recrystallization with a face-centered cubic (FCC) structure. Tensile testing results indicated a subtle anisotropy in the yielding, and after heat treatment, a significant enhancement in ductility was observed. A study of the shape memory effect demonstrated that the as-printed samples exhibited an FCC-HCP dual-phase structure, which transformed into an FCC single-phase structure after heat treatment. The application of external loading induced reformation of the HCP phase, successfully demonstrating the shape memory effect in the alloy, with a maximum recovery strain of 0.79 %.