Palladium fabricated on Fe3O4 as an organic-inorganic hybrid nanocatalyst for the Suzuki and Stille coupling reactions

•This is the first report of this catalyst.•Nanocatalyst can be recovered and reused without decreasing catalytic activity.•Nanocatalyst characterized by BET, FT-IR, EDS, SEM, TGA, XPS, XRD, ICP, TEM, and VSM technique. The Fe3O4@L-Threonine-Pd complex, comprising palladium supported on modified Fe3...

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Veröffentlicht in:Journal of molecular structure 2025-02, Vol.1321, p.139597, Article 139597
Hauptverfasser: Saleh, Mohanad Yakdhan, Aldulaimi, Ahmed Kareem Obaid, Saeed, Shakir Mahmood, Adhab, Ayat Hussein
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Sprache:eng
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Zusammenfassung:•This is the first report of this catalyst.•Nanocatalyst can be recovered and reused without decreasing catalytic activity.•Nanocatalyst characterized by BET, FT-IR, EDS, SEM, TGA, XPS, XRD, ICP, TEM, and VSM technique. The Fe3O4@L-Threonine-Pd complex, comprising palladium supported on modified Fe3O4 magnetic nanoparticles (MNPs), has been documented for its use in Stille and Suzuki coupling reactions. The catalyst's environmental friendliness was assessed through a range of techniques including vibrating sample magnetometry (VSM), Fourier-transform infrared spectroscopy (FTIR), inductively coupled plasma (ICP), X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), energy dispersive X-ray photoelectron spectroscopy (XPS), and X-ray spectroscopy (EDS). Using an external magnet, it is easy to separate nanoparticles from the mixture. The nanocatalyst underwent Metal leaching and heterogeneity testing using the ICP-OES technique, demonstrating its ability to be recovered and reused multiple times without a significant loss of catalytic efficiency or palladium leaching. [Display omitted]
ISSN:0022-2860
DOI:10.1016/j.molstruc.2024.139597