Influence of L-tyrosine on dynamics of Bray-Liebhafsky oscillatory reaction in batch reactor. Experimental investigation and numerical modeling

•Experimental analysis shows strong influence of l-Tyrosine on the oscillatory dynamics of the Bray-Liebhafsky reaction.•Two reaction pathways based on the interaction of l-Tyrosine with HIO or I2O were investigated to explain the experimental results.•The reaction pathway between l-Tyrosine and I2O...

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Veröffentlicht in:Journal of molecular structure 2024-09, Vol.1311, p.138466, Article 138466
Hauptverfasser: Maksimović, Jelena, Ivanović-Šašić, Ana, Maćešić, Stevan, Čupić, Željko
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Sprache:eng
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Zusammenfassung:•Experimental analysis shows strong influence of l-Tyrosine on the oscillatory dynamics of the Bray-Liebhafsky reaction.•Two reaction pathways based on the interaction of l-Tyrosine with HIO or I2O were investigated to explain the experimental results.•The reaction pathway between l-Tyrosine and I2O showed better agreement with the experimental results. The impact of L-tyrosine on the dynamics of the Bray-Liebhafsky (BL) oscillatory reaction was investigated both experimentally and numerically. The study focused on the examination of the sensitivity of the BL reaction to L-tyrosine perturbation. The results obtained indicated possible pathways of influence. Simulations were carried out with and without L-tyrosine. The interaction of L-tyrosine with the BL reaction system was tested with two possible reactions. [Display omitted]
ISSN:0022-2860
1872-8014
DOI:10.1016/j.molstruc.2024.138466