Anticorrosion propriety of new resin epoxy derived from phosphorus as inhibitor of steel corrosion in 0.5 M H2SO4

•This study is for aim to evaluate the performance of PBA resin as corrosion inhibitor.•This study performed for the carbon steel in acidic medium (0.5 M H2SO4) at room temperature, by the weight loss and electrochemical methods and the surface investigated using SEM/EDS and AFM.•The results showed...

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Veröffentlicht in:Journal of molecular structure 2023-12, Vol.1294, p.136491, Article 136491
Hauptverfasser: Abbout, Said, Hsissou, Rachid, Louiza, Ouksel, Bourzami, Riadh, Erramli, Hamid, Chebabe, Driss, Hajjaji, Najat
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Sprache:eng
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Zusammenfassung:•This study is for aim to evaluate the performance of PBA resin as corrosion inhibitor.•This study performed for the carbon steel in acidic medium (0.5 M H2SO4) at room temperature, by the weight loss and electrochemical methods and the surface investigated using SEM/EDS and AFM.•The results showed that the corrosion inhibition behavior of inhibitor is excellent in sulfuric acid.•The experimental result confirmed by a theoretical study. This paper aims to study the performance of the pentaglycidyl ether pentabisphenol A of phosphorus (PBA) as corrosion inhibitor for carbon steel (E24) in 0.5 M H2SO4. This study has performed using gravimetric measurements, electrochemistry measurements such as potentiodynamic and electrochemical impedance spectroscopy techniques, and surface analysis (SEM/EDS). The results show that the PBA has good anticorrosive behavior against the 0.5 M H2SO4 solution; the inhibition efficiency reached 96.25% for 10−3 M of PBA. The adsorption isotherm of Langmuir indicates the existence of a chemical chemisorption of the PBA on the metal surface (∆G* = –44.23 Kj/mol). The nature and properties of the protective layer on the steel surface were verified by scanning electron microscopy (SEM)/energy dispersive X-ray spectroscopy (EDX).
ISSN:0022-2860
1872-8014
DOI:10.1016/j.molstruc.2023.136491