Influence of typical liquid fuels on foam properties of critical components of environmentally friendly aqueous film-forming foams
•Molecular interaction is affected by oils with different density and emulsification.•Foamability decreases under fuel due to emulsification between fuel and surfactants.•Presence of liquid fuel accelerates foam drainage and liquid film thinning behavior.•Oil resistivity of foam depends on differenc...
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Veröffentlicht in: | Journal of molecular liquids 2024-05, Vol.401, p.124695, Article 124695 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | •Molecular interaction is affected by oils with different density and emulsification.•Foamability decreases under fuel due to emulsification between fuel and surfactants.•Presence of liquid fuel accelerates foam drainage and liquid film thinning behavior.•Oil resistivity of foam depends on difference in nature and emulsification of oils.
In this study, the influence mechanism of typical fuels (oils) on the foam properties of mixture of hydrocarbon and fluorocarbon surfactants was investigated. A mixed solution was prepared based on a nonionic hydrocarbon surfactant (APG-0810) and a zwitterionic C6 fluorocarbon surfactant (short-chain). The effect of different oils (heptane, kerosene, diesel, and transformer oil) on the physical property parameters, foamability, oil resistivity of foam and single vertical liquid film of the mixture are systematically investigated. Results indicate that the viscosity of mixture increases, but the conductivity, surface activity, and initial foam height decreases with addition of the four oils. The drainage and volume decay of the foam are accelerated by the presence of oils. In addition, the presence of oils accelerates liquid film thinning through affecting drainage, especially for the oil with higher density, water solubility, and volatility. The four oils showed different effect on foam properties due to the difference in nature and emulsification of them. Among them, the foam properties under the action of heptane is the best, and the oil resistivity of foams is the best. This study can provide theoretical guidance for oil resistivity of hydrocarbon and fluorocarbon surfactant stabilized foams. |
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ISSN: | 0167-7322 1873-3166 |
DOI: | 10.1016/j.molliq.2024.124695 |