Bent-core liquid crystals joining the ethylene-oxide/lithium ion tandem: Ionic conductivity and dielectric response towards new electrolytes for energy applications

[Display omitted] •Bent-core liquid crystals containing tetra(ethylene-oxide) moieties were doped with lithium triflate salts.•The doped materials display smectic mesophases inside indium tin oxide cells.•Lithium ions are selectively solvated in the ethylene-oxide blocks.•The presence of lithium ions promotes direct current conductivity at low frequencies.•The materials show potential as new nanostructured electrolytes, controllable by light irradiation. We report the dielectric and conductivity response of three materials containing bent-core and tetra(ethylene-oxide) moieties, and their complexes doped with lithium triflate salts, as new potential nanostructured electrolytes. Whilst the pristine bent-core compounds do not show mesomorphism, the doped materials display smectic mesophases inside indium tin oxide cells assisted by the selective solvation of the lithium ions in the ethylene-oxide blocks. The dielectric response of the materials in the high-frequency range is controlled by the chemical composition of the bent-core structure, and the presence of lithium ions promotes direct current conductivity at low frequencies, in the σdc ∼ 10-5 S cm−1 range, which can be enhanced to σdc ∼ 10-4 S cm−1 via trans-to-cis photoisomerization of azobenzene groups. The dynamic and dual character of these materials (responding to low and high frequency electrical fields), the formation of ferroelectric crystals capable to store energy, and their interactions with light, will be applied to develop new energy devices.