Graphene oxide-manganese ferrite (GO-MnFe2O4) nanocomposite: One-pot hydrothermal synthesis and its use for adsorptive removal of Pb2+ ions from aqueous medium

Herein, we showed that the graphene oxide with manganese ferrite (GO-MnFe2O4) possess great adsorption properties for the selective Pb2+ ions removal from the aqueous medium. Nanocomposite adsorbent was developed by one-pot hydrothermal method, using graphene oxide as a supporting material to minimi...

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Veröffentlicht in:Journal of molecular liquids 2020-10, Vol.315, p.113769, Article 113769
Hauptverfasser: Verma, Monu, Kumar, Ashwani, Singh, Krishna Pal, Kumar, Ravi, Kumar, Vinod, Srivastava, Chandra Mohan, Rawat, Varun, Rao, Gyandeshwar, Kumari, Sujata, Sharma, Pratibha, Kim, Hyunook
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Sprache:eng
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Zusammenfassung:Herein, we showed that the graphene oxide with manganese ferrite (GO-MnFe2O4) possess great adsorption properties for the selective Pb2+ ions removal from the aqueous medium. Nanocomposite adsorbent was developed by one-pot hydrothermal method, using graphene oxide as a supporting material to minimize the aggregation of MnFe2O4. Also, GO possesses important role in the adsorption mechanism of Pb2+ through electrostatic/ionic interactions. The characterizations such as FT-IR, XPS, P-XRD, FE-SEM, and BET of the synthesized nanocomposite were carried out to assess the different properties such as functionalities, crystallinity, morphology, and surface area value, respectively. Thereafter, the adsorption performance of GO-MnFe2O4 nanocomposite was tested for the Pb2+ at various adsorption parameters including to contact time, solution pH, adsorbent dose, and concentration of initial Pb2+ in order to measure the optimum adsorption condition. Kinetic experiments suggest that the equilibrium attained in 30 min and followed a pseudo-second-order kinetic model. Adsorption isotherm model followed to Langmuir isotherms and gives a maximum adsorption capacity of 621.11 mg/g. The reusability tests exhibited good durability and good efficiency for repeated Pb2+ adsorptions with GO-MnFe2O4 nanocomposite. These results demonstrated that the GO-MnFe2O4 nanocomposite may be an attractive adsorbent having low-cost for the effectively Pb+2 removal of from the polluted water. [Display omitted] •GO-MnFe2O4 nanocomposite synthesized using one-pot hydrothermal•A better enhancement in the Pb2+ adsorption occurs in aqueous solution.•Maximum adsorption capacity was found to be 621.11 mg/g.•Adsorption equilibrium occurs after 30 min, and followed to the pseudo-second order kinetic model.•Adsorption followed to Langmuir isotherm model (monolayer adsorption)
ISSN:0167-7322
1873-3166
DOI:10.1016/j.molliq.2020.113769