Seed-assisted direct synthesis of aluminosilicate form of ITQ-58 zeolite

The aluminosilicate form of ITQ-58 has been directly synthesized in the synthesis gel SiO2-Al2O3-Na2O-H2O using Si/B-ITQ-58 zeolite as seed. Si/Al-ITQ-58 exhibits good crystallinity, high surface area, tetrahedral Al3+ species, and middle acid sites. The acidic form of Si/Al-ITQ-58 zeolite, is an ex...

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Veröffentlicht in:Microporous and mesoporous materials 2021-10, Vol.326, p.111362, Article 111362
Hauptverfasser: Huang, Qintong, Chen, Ningyue, Wen, Mengyun, Liang, Weichi, Li, Rui, Zhao, Yukai, Zeng, Zhifeng, Zhang, Chuanqi, Jiang, Jiuxing
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Sprache:eng
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Zusammenfassung:The aluminosilicate form of ITQ-58 has been directly synthesized in the synthesis gel SiO2-Al2O3-Na2O-H2O using Si/B-ITQ-58 zeolite as seed. Si/Al-ITQ-58 exhibits good crystallinity, high surface area, tetrahedral Al3+ species, and middle acid sites. The acidic form of Si/Al-ITQ-58 zeolite, is an excellent alternative heterogeneous catalyst with high yield and simple product separation, used for Biginelli reaction. Therefore, with the second case, we further confirm the new function of seed-assisted synthesis, i.e., direct aluminosilicate preparation. The aluminosilicate form of ITQ-58 has been directly synthesized in the synthesis gel SiO2-Al2O3-Na2O-H2O using Si/B-ITQ-58 zeolite as seed, which further confirm the new function of seed-assisted synthesis, i.e., direct aluminosilicate preparation. [Display omitted] •The aluminosilicate form of ITQ-58 has been directly synthesized in the inorganic synthesis gel using Si/B-ITQ-58 zeolite as seed.
ISSN:1387-1811
1873-3093
DOI:10.1016/j.micromeso.2021.111362