Occurrence of the UV-filter 2-Ethylhexyl 4-methoxycinnimate (EHMC) in Antarctic snow: First results

[Display omitted] •For the first time, EHMC is found in Antarctic snow samples.•Possible emissions from local human presence in Antarctica.•Levels and distribution consistent with long-range transport models. The distribution of Personal Care Products in Antarctica is still far from being well docum...

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Veröffentlicht in:Microchemical journal 2022-12, Vol.183, p.108060, Article 108060
Hauptverfasser: D'Amico, Marianna, Gambaro, Andrea, Barbante, Carlo, Barbaro, Elena, Caiazzo, Laura, Vecchiato, Marco
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Sprache:eng
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Zusammenfassung:[Display omitted] •For the first time, EHMC is found in Antarctic snow samples.•Possible emissions from local human presence in Antarctica.•Levels and distribution consistent with long-range transport models. The distribution of Personal Care Products in Antarctica is still far from being well documented. A pilot study was conducted to evaluate the presence of organic UV filters in Antarctica using GC–MS/MS. The 2-Ethylhexyl 4-methoxycinnimate (EHMC), also known as octinoxate, was detected for the first time in Antarctic surface snow, and also in snowmelt and ponds with concentrations from 0.4 ng/L up to 3.1 ng/L. In this pristine environment, human activities in scientific bases and facilities are a potential primary local source of EHMC. However, the results presented in this study suggest that long-range sources might also be responsible for the presence of EHMC in Antarctica. Considering the physicochemical properties of EHMC, long-range atmospheric transport is plausibly a relevant process involved in its deposition and accumulation in Antarctic snow. Two modelling studies on contaminants' long-range transport potential are compared to investigate the behaviour of EHMC in polar environments and its transport potential.
ISSN:0026-265X
1095-9149
DOI:10.1016/j.microc.2022.108060