Fabrication of high-selective hollow fiber DD3R zeolite membrane modules for high-pressure CO2/CH4 separation

All-silica Decadodecasil 3 R (DD3R) zeolite membranes, possessing small pore size of 0.36 nm × 0.44 nm, have been attractive in CO2 removal from natural gas. In this work, hollow fiber DD3R zeolite membrane modules with membrane length of 40 cm and effective membrane area of 811 cm2 for each were successfully fabricated by ensemble synthesis strategy. Different membrane segments including that was grown on sealing glaze have similar thickness in the range of 4–6 μm. The ozone detemplation time of membrane unit was reduced by a half with the assistance of Teflon spiral column. The resulting membrane module exhibited a good CO2/CH4 separation selectivity (105) as well as a stage-cut of 25.7% at high feed pressure of 3.1 MPa. Effects of feed pressure, feed gas flow rate and permeate pressure on separation performance of the membrane module and concentration polarization were investigated extensively. When the feed gas flow rate was 2 L min−1, the retentate CO2 concentration was lowered to 9.45% and the CH4 loss was limited to 4.87% at the feed and permeate pressures of 3.1 MPa and 2 kPa. The concentration polarization effect became more serious at higher feed pressure or lower feed gas flow rate. [Display omitted] •Hollow fiber DD3R membranes modules were fabricated by ensemble synthesis strategy.•The hollow fiber membrane module has membrane are of 811 cm2.•Membrane module showed a CO2/CH4 separation selectivity of 105 at 3.1 MPa.•Effect of separation conditions on concentration polarization was discussed.