Low-amount palladium supported on Fe-Cu MOF: Synergetic effect between Pd, Cu and Fe in Sonogashira-Hagihara coupling reaction and reduction of organic dyes
•FeCu MOF prepared via solvothermal method followed by Pd incorporation.•Pd(II)@NH2BDC-FeCu MOF as effective catalyst in Sonogashira couplings reaction and the reduction of organic dyes.•Catalytic system recyclable and reusable for six sequential times. FeCu MOF has been prepared via solvothermal me...
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Veröffentlicht in: | Molecular catalysis 2022-04, Vol.522, p.112199, Article 112199 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | •FeCu MOF prepared via solvothermal method followed by Pd incorporation.•Pd(II)@NH2BDC-FeCu MOF as effective catalyst in Sonogashira couplings reaction and the reduction of organic dyes.•Catalytic system recyclable and reusable for six sequential times.
FeCu MOF has been prepared via solvothermal method and the resulting bimetallic MOF was employed for stabilization of Pd species. Obtained Pd(II)@NH2BDC-FeCu MOF could act as an effective environmental catalyst in Sonogashira-Hagihara coupling reaction and the reduction of organic dyes. This recyclable catalyst demonstrated high catalytic activity for Sonogashira reaction of aryl iodides and aryl bromides with alkynes. Rhodamine B and methyl red as organic dyes were instantly reduced. Pd(II)@NH2BDC-FeCu/MOF was characterized by TEM, XPS, FT-IR, BET, XRD, and SEM. In addition, the synthesized catalyst was recyclable and reusable for 6 sequential times without deteriorating remarkable in catalytic performance for reaction of iodobenzene with phenylacetylene.
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ISSN: | 2468-8231 2468-8231 |
DOI: | 10.1016/j.mcat.2022.112199 |