Synthesis of BaAl2Ge2O8 by the Pechini method, using graphene oxide as stabilizing agent
•BaAl2Ge2O8 (BAG) has been synthesized by the Pechini method for the first time.•Graphene oxide, as a stabilizing agent, enables the obtention of the pure BAG phase.•The formation of irregular-shaped BAG flakes between grains was promoted by GO. In this study, BaAl2Ge2O8 (BAG) synthesis was performe...
Gespeichert in:
Veröffentlicht in: | Materials letters 2024-07, Vol.367, p.136559, Article 136559 |
---|---|
Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | •BaAl2Ge2O8 (BAG) has been synthesized by the Pechini method for the first time.•Graphene oxide, as a stabilizing agent, enables the obtention of the pure BAG phase.•The formation of irregular-shaped BAG flakes between grains was promoted by GO.
In this study, BaAl2Ge2O8 (BAG) synthesis was performed using the Pechini method for the first time. Graphene oxide (GO), used as a precursor agent to obtain the pure phase of BAG, was incorporated to the precursor powders before heath treatment at 1300 °C. The pure BAG phase was obtained with a cation:citric acid molar ratio of 8:1, a pH = 8, and a mass concentration of GO from 0.5 wt%. The incorporation of 2 wt% of GO promoted the formation of irregular-shaped BAG flakes with a size smaller than 3 µm. The pure BAG phase exhibited a band gap of 5.12 eV. |
---|---|
ISSN: | 0167-577X 1873-4979 |
DOI: | 10.1016/j.matlet.2024.136559 |