Self-single-doped hierarchical porous carbon nanofiber derived Alpinia galanga stem-based for boosted supercapacitor performance

[Display omitted] •Self-O-doped Alpinia galanga stem-based carbon nanofiber succesfully synthesis.•The hierarchical porous carbon exhibit high specific surface area of 1065.58 m2/g.•The porous carbon was performed in solid-free binder form.•In 2-electrode system, supercapacitor possessed specific ca...

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Veröffentlicht in:Materials letters 2024-04, Vol.360, p.135954, Article 135954
Hauptverfasser: Taer, Erman, Nursyafni, Nursyafni, Febriani, Widya, Apriwandi, Apriwandi, Manjunatha, Jamballi G., Deraman, Mohamad, Taslim, Rika
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Sprache:eng
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Zusammenfassung:[Display omitted] •Self-O-doped Alpinia galanga stem-based carbon nanofiber succesfully synthesis.•The hierarchical porous carbon exhibit high specific surface area of 1065.58 m2/g.•The porous carbon was performed in solid-free binder form.•In 2-electrode system, supercapacitor possessed specific capacitance of 226F g−1. In this study, activated carbon with hierarchical pores and a nanofiber structure doped with oxygen was prepared using a pure biomass-based sustainable strategy involving integrated chemical impregnation and pyrolysis. Alpinia galangal stem was chosen as it functions as fast conductive network with abundant electrochemical active sites for high-grade electrode materials. The optimal precursor exhibited self-doping of oxygen ranging from 6.15 to 15.69 % with 1065.58 m2/g, which contributed to the redox reaction of the electrode material. When tested in a 2-electrode system, the porous carbon nanofibers showed a high specific capacitance of 226F g−1 at 1 A g−1 in 1 M H2SO4 electrolyte, producing an energy density of 9.3483 Wh kg−1 with a coulombic efficiency of 89.01 %. The results showed that oxygen-doped hierarchical porous carbon nanofibers produced from Alpinia galangal stem biomass and designed to be solid-free of binders are highly promising as high-quality electrode materials that can improve sustainable supercapacitor performance.
ISSN:0167-577X
1873-4979
DOI:10.1016/j.matlet.2024.135954