Pb3BP3O12: A new congruent-melting compound with one-dimensional zigzag chains

Pb3BP3O12: A new congruent-melting compound with one-dimensional zigzag chains

•PBP crystal was grown.•PBP featured zigzag chains.•PBP melted congruently. A new single crystal of Pb3BP3O12 (PBP) was grown by top seeded growth method with the crystal dimensional of 18 mm × 7 mm × 9 mm. Pb3BP3O12 was a congruent-melting compound and crystallized in the orthorhombic space group o...

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Veröffentlicht in:Materials letters 2023-11, Vol.351, p.135053, Article 135053
Hauptverfasser: Shi, Yunjing, Liu, Zunqi, Abuduwaili, Aytursun, Han, Shujuan
Format: Artikel
Sprache:eng
Schlagworte:
Crystal growth
Crystal structure
Pb3BP3O12
Zigzag chains
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Zusammenfassung:•PBP crystal was grown.•PBP featured zigzag chains.•PBP melted congruently. A new single crystal of Pb3BP3O12 (PBP) was grown by top seeded growth method with the crystal dimensional of 18 mm × 7 mm × 9 mm. Pb3BP3O12 was a congruent-melting compound and crystallized in the orthorhombic space group of Ibca with unit cell parameters of a = 7.0080(2) Å, b = 14.2286(4) Å, c = 21.5469(6) Å and Z = 8. The structure featured a one-dimensional (1D) zigzag chains composed of [B(PO4)3]6- anionic units. Pb atoms located between the anion chains to connect them, forming a 3D network structure. Furthermore, Pb3BP3O12 performed a wide transmittance range from 250 to 2600 nm.
ISSN:0167-577X
1873-4979
DOI:10.1016/j.matlet.2023.135053