Multi-functional carbon dots for visual detection of picric acid and white-light emission
[Display omitted] •The single-pot, fast and facile synthesis protocol for multi-functional carbon dots (CDs).•The selective and sensitive detection of picric acid, via luminescence quenching of CDs.•White-light emission was realized using Poly vinyl alcohol (PVA)-CDs composite as a the colour conver...
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Veröffentlicht in: | Materials research bulletin 2021-06, Vol.138, p.111223, Article 111223 |
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Sprache: | eng |
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•The single-pot, fast and facile synthesis protocol for multi-functional carbon dots (CDs).•The selective and sensitive detection of picric acid, via luminescence quenching of CDs.•White-light emission was realized using Poly vinyl alcohol (PVA)-CDs composite as a the colour converting phosphor.
Herein we report the synthesis of multifunctional carbon dots (CDs) through microwave-assisted pyrolysis of 2-aminoterephthalic acid and polyethylene glycol. The CDs exhibited relatively high photoluminescence quantum yield of about 67 %, and has been found to be selective and ultrasensitive to the nitroaromatic explosive picric acid, with a detection limit as low as 18 nM. The visual detection of the analyte was realized using CDs in the solid-phase, after coating the dots on silica-based thin-layer chromatographic plates. Furthermore, the broad-band luminescence was exploited for UV-to-visible light conversion, to obtain the color parameters of CIE (0.35, 0.33), CRI of 92 and CCT of 5246 K, representing the cool, white-gamut region of 1931 CIE chromaticity diagram. |
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ISSN: | 0025-5408 1873-4227 |
DOI: | 10.1016/j.materresbull.2021.111223 |