Atomically dispersed cerium species in NMxCe1-xO2/Al2O3 (NM = Rh, Ru) catalysts

[Display omitted] •HAADF-STEM revealed atomically dispersed CeOx species in NM1-xCexO2/γ-Al2O3 catalysts.•CeOx species may order at the surface of γ-Al2O3 support.•Concentration of CeOx species increases after reduction treatment at high temperature.•Spreading of CeOx over alumina explains the amorp...

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Veröffentlicht in:Materials research bulletin 2020-02, Vol.122, p.110673, Article 110673
Hauptverfasser: Ledwa, K.A., Kepinski, L., Pawlyta, M.
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Sprache:eng
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Zusammenfassung:[Display omitted] •HAADF-STEM revealed atomically dispersed CeOx species in NM1-xCexO2/γ-Al2O3 catalysts.•CeOx species may order at the surface of γ-Al2O3 support.•Concentration of CeOx species increases after reduction treatment at high temperature.•Spreading of CeOx over alumina explains the amorphiztion of ceria observed by XRD. NMxCe1-xO2/Al2O3 (NM = Rh, Ru; 0 
ISSN:0025-5408
1873-4227
DOI:10.1016/j.materresbull.2019.110673