The effect of solvent polarity on emission properties of carbon dots and their uses in colorimetric sensors for water and humidity

[Display omitted] •Carbon dots (CDs) have successfully been formed from NTA and p-PD as novel precursors via solvothermal synthesis.•CDs show strong solvatochromic property which results from the edge N structure and the solvation effect.•CDs exhibit an excellent ability to detect water in organic s...

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Veröffentlicht in:Materials research bulletin 2019-11, Vol.119, p.110564, Article 110564
Hauptverfasser: Lee, Hye Jin, Jana, Jayasmita, Thi Ngo, Yen-Linh, Wang, Lin Lin, Chung, Jin Suk, Hur, Seung Hyun
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Sprache:eng
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Zusammenfassung:[Display omitted] •Carbon dots (CDs) have successfully been formed from NTA and p-PD as novel precursors via solvothermal synthesis.•CDs show strong solvatochromic property which results from the edge N structure and the solvation effect.•CDs exhibit an excellent ability to detect water in organic solvents because of water-induced red shift fluorescence. Carbon dots have emerged as promising nanomaterials because of their outstanding properties. The issue is to obtain multicolor emissions of carbon dots. Carbon dots from aliphatic acids and aromatic amines have successfully been synthesized, and their emission properties are controlled easily by solvents. This study helps deepen our understanding of the solvent-dependent behavior of nitrogen-doped carbon dots, especially their solvent polarity effects. The physical, chemical, and optical properties of carbon dots were analyzed, and the possibility of their use for detecting water in organic solvents and as paper-based humidity sensors was demonstrated.
ISSN:0025-5408
1873-4227
DOI:10.1016/j.materresbull.2019.110564