Synthesis and characterization of a nanocatalyst consisting of tungsten (VI) oxide and ruthenium for potential use in the hydrogen generation via hydrolysis of methylamine-borane

The demand for effective and safe chemical storage systems as an alternative energy carrier is unabated. This study reports the analysis of methylamine-borane (MeAB) as a new, efficient, and widely applicable technological storage material for mobile applications. Here, we report the preparation of tungsten (VI) oxide (WO3) supported ruthenium (Ru) nanoparticles (Ru/WO3) by impregnation-reduction method and their use as a nanocatalyst in the hydrolysis of MeAB for hydrogen (H2) production. Ru/WO3 nanocatalyst was characterized by a combination of advanced analytical tools such as XRD, XPS, TEM, TEM-EDX, SEM, and SEM-EDX. Ru/WO3 nanocatalyst, with an average particle size of 2.16 ± 0.23 nm obtained from TEM analysis, produces H2 at 298 K with an initial turnover frequency (TOFinitial) value of 43.57 min−1 in complete conversion in the hydrolysis of MeAB. In addition, the activation energy (Ea#), activation enthalpy (ΔH#) and activation entropy (ΔS#) values of the Ru/WO3 nanocatalyst were calculated as in MeAB hydrolysis are 51.54 kJ/mol, 3.7 kJ/mol and 184.57 J/mol × K, respectively, from the Arrhenius and Eyring-Polanyi equations. It was concluded that both the calculated TOFinitial value and activation parameters were quite valuable compared to previous catalysts used for MeAB hydrolysis. [Display omitted] •WO3-supported Ru (0) NPs (Ru/WO3) were successfully synthesized and defined.•Catalytic activity of Ru/WO3 is 43.57 min−1 for MeAB hydrolysis in terms of TOFinitial.•Activation parameters were calculated as Ea# = 51.54 kJ/mol, ΔH# = 3.7 kJ/mol and ΔS# = −184.57 J/mol × K.•Ru/WO3 was recyclable and could be reused for at least ten times.