Flash sintering of ZrO2–SnO2–ZrSnO4 composite nanofibers: Fabrication, properties, and biochemical effects in Drosophila melanogaster
ZrO2–SnO2–ZrSnO4 composite nanofibers (CNFs) were fabricated by an electrospinning technique in three different ratios by volume (%v/v). Changing the composition ratio of CNFs affected the temperature and sinter time variation of both the band gap and the flash sintering (FS) phenomenon. FS experime...
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Veröffentlicht in: | Materials chemistry and physics 2024-07, Vol.320, p.129421, Article 129421 |
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Sprache: | eng |
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Zusammenfassung: | ZrO2–SnO2–ZrSnO4 composite nanofibers (CNFs) were fabricated by an electrospinning technique in three different ratios by volume (%v/v). Changing the composition ratio of CNFs affected the temperature and sinter time variation of both the band gap and the flash sintering (FS) phenomenon. FS experiments were used at a current cut-off of 3.77 mA/mm2 under thermal (844–878 °C) and electric field (420 V/mm). Highly dense CNFs were obtained in less than 80 s with a maximum power absorption of 1.58 W/mm3. In addition to the FS process, CNFs were sintered with the conventional sintering (CS) method at 1200 °C for 1 h. As the amount of Sn in the composition (%v/v) increases, the density increases, but the hardness value decreases. The FS process was proven to produce faster, denser, and harder material than CS.
Long-term and permanent results are obtained by designing biocompatible nanocomposite materials in health. However, determining the long-term effects of CNFs, which are considered non-toxic, is necessary. Drosophila melanogaster female food was covered with these different v/v% ratios CNFs (ZrSn, Zr2Sn; 2ZrSn) and contact by life span: The effects were evaluated on movement, weight, egg production, longevity, and antioxidant system (Superoxide dismutase-SOD, catalase-CAT, glutathione-GSH, and 2,2-diphenyl-1-picrylhydrazil-DPPH). It can be said that Zr2S CNFs were not toxic by not changing the life span, egg production, climbing, and biochemical parameters of the fly. However, it was determined that CNFs used in ZrSn and 2ZrSn ratios slightly reduced the behavioral (movement and longevity) and antioxidant activities (SOD and CAT) of the individual.
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•CS, density, and hardness tests of ZrO2-SnO2-ZrSnO4 CNFs (ternary system) were investigated.•The FS, yielded a short-time process, denser and harder compositions compared to CS.•The long-term toxicity of FS ZrO2-SnO2-ZrSnO4 CNFs did not produce short-term toxicity using Drosophila melanogaster.•In aging flies, ZrSn and 2ZrSn CNFs decreased SOD and CAT activity and resulting in weight gain and reduced locomotion.•Flies in groups 2 and 4 had a reduced lifespan because of continuous contact with CNFs. |
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ISSN: | 0254-0584 1879-3312 |
DOI: | 10.1016/j.matchemphys.2024.129421 |