Preparation of a nickel-cobalt-zinc alloy coating as SOFC connection material in deep eutectic solvent

The Ni-Co-Zn alloy coating is prepared in a deep eutectic solvent system using pulse power supply technology, and the feasibility of the deep eutectic solvent system as an electrolyte is confirmed through infrared spectroscopy and cyclic voltammetry. The microscopic morphology analysis shows that th...

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Veröffentlicht in:Materials chemistry and physics 2024-04, Vol.317, p.129071, Article 129071
Hauptverfasser: Li, Bowen, Zheng, Chuanbo, Pan, Chengyu, Pan, Fengze, Lv, Tianyi, Wang, Xiaotian, Ju, Xiang, Gong, Kaifei, Zou, Wenkai, Yi, Guo
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Sprache:eng
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Zusammenfassung:The Ni-Co-Zn alloy coating is prepared in a deep eutectic solvent system using pulse power supply technology, and the feasibility of the deep eutectic solvent system as an electrolyte is confirmed through infrared spectroscopy and cyclic voltammetry. The microscopic morphology analysis shows that the plating layer is uniform and dense, and the grains are spherical particles, and it is detected that the oxidized weight gain rate of the plating layer is 7.6842 × 10−8 g2 cm−4·h−1 at 900 °C, which is 3 orders of magnitude different from the oxidation rate constant of the substrate. The corrosion potential increases to −0.281 V in 3.5 % NaCl solution, and the corrosion current density decreases to 3.259 × 10−7 (A/cm2), with an ASR of 43.64 mΩ cm2 at 800 °C. The results indicate that the Ni-Co-Zn coating can meet the requirements for an SOFC connector material. •The Ni-Co Zn coating is prepared by low eutectic solvent system.•The results show that higher current density leads to hydrogen evolution.•The corrosion resistance of the coating is better than that of the substrate.•The oxidation resistance of the coating is better than that of the substrate.
ISSN:0254-0584
1879-3312
DOI:10.1016/j.matchemphys.2024.129071