Trends in thermal maturity indicators for the organic sulfur-rich Eagle Ford Shale

Thermal maturity is critical to evaluate petroleum systems and to interpret biomarker results for paleoenvironmental and geobiology studies. Many thermal maturity indices were developed for marine source rocks containing type II kerogen, but their behavior in organic sulfur-rich source rocks requires more investigation. Here, we present geochemical analyses of whole and extracted rock, isolated kerogen, and extractable organic matter across a natural thermal maturity sequence of the Upper Cretaceous Eagle Ford Shale to evaluate the behavior of maturity parameters in organic sulfur-rich source rocks. The samples have similar mineralogy and trace element composition, minimizing potential facies effects on thermal maturity parameters. Atomic H/C ratios of isolated kerogen, extractable organic matter yield, and programmed pyrolysis results show that the samples range from the pre-oil through dry gas generation windows. Programmed pyrolysis data and kerogen elemental ratios show that the immature samples host both type IIS (atomic Sorg/C > 0.04) and sulfur-rich type II kerogen (kerogen Sorg/C: 0.03–0.04) while samples with lower kerogen Sorg/C ratios (kerogen Sorg/C