Bimodal volcanic rocks in the northeastern margin of the Yangtze Block: Response to breakup of Rodinia supercontinent

Mid-Neoproterozoic protoliths of high–ultrahigh-pressure metamorphic rocks in the northeastern margin of the Yangtze Block preserve one of the best examples of 18O-depleted magmatic provinces worldwide, which is the significant record for lithospheric extension associated with continental rifting. In this contribution, we report the depleted 18O signature of felsic meta-volcanic rocks from the Zhangbaling Uplift (ZBLU), a segment of the Tan–Lu fault zone, which is located between the Dabie and Sulu orogenic belts. The low-δ18O signature of these rocks provides crucial information for understanding their origin and tectonic setting. Zircons yield UPb protolith ages of 771 ± 5 Ma to 761 ± 5 Ma and show a narrow range in δ18O values of 1.97‰ to 3.11‰. The typical syn-magmatic characteristics of these zircons indicate that they record inheritance from low-δ18O magmas during the mid-Neoproterozoic, which suggests the occurrence of high-temperature surface-water–rock interaction in a continental rift setting. Quartz keratophyres in the ZBLU exhibit A-type granite geochemical compositions with high contents of high-field-strength elements (Zr + Nb + Ce + Y > 350 ppm) and a zircon saturation temperature of 829 °C. The zircon grains have slightly depleted εHf(t) values of −3.4 to +1.9, which suggest Mesoproterozoic juvenile crustal formation in response to the amalgamation of the Yangtze Block with the Rodinia supercontinent. A few coeval spilites (758 Ma) crop out sporadically in the ZBLU. Their geochemical characteristics include high SiO2 contents (51.06–57.03 wt%), low Mg# values (42–53), and arc-like trace-element distribution patterns. The variable zircon εHf(t) values for the spilite samples can be divided into two groups: negative εHf(761 Ma) values of −16.4 to −11.1, and positive εHf(744 Ma) values of +5.9 to +8.5, which supports source mixing between enriched mantle and residual oceanic crustal material. In conclusion, the ZBLU spilite–keratophyre sequence is composed of a typical bimodal rock association, providing new petrological evidence for the origin of low-δ18O magmas and for a continental rift setting related to the separation of the Yangtze Block from the Rodinia supercontinent at ca. 771 Ma. •Mid-Neoproterozoic bimodal magma events were identified in the Zhangbaling Group.•Quartz keratophyres are A-type and display low zircon δ18O values (1.97–3.11‰).•Spilites derived from mixing between enriched mantle and residual oceanic crust.•The bimodal vo