Petrogenesis of gold-bearing listvenites from the carbonatized mantle section of the Neoproterozoic Ess ophiolite, Western Arabian Shield, Saudi Arabia

The variably serpentinized mantle peridotites of the Late Neoproterozoic Ess ophiolite (Western Saudi Arabia) are highly altered along shear zones and thrust planes to form erosion-resistant listvenites. The listvenites are distinguished petrographically and geochemically into three types: carbonate, silica-carbonate and silica (birbirite) listvenites. Geochemical analyses are consistent with expectations from petrography: carbonate listvenite is low in SiO2 content but high in MgO, Fe2O3, and CaO relative to silica-carbonate and birbirite, which is remarkably high in SiO2 at the expense of all other components. The total REE contents are low in silica-carbonate and carbonate listvenites but highly enriched in birbirite, with a large positive Eu anomaly. The host serpentinites have all the characteristics typically associated with highly depleted mantle harzburgite protoliths in supra-subduction fore-arc settings: bulk compositions are low in Al2O3 and CaO with high Mg# [molar Mg/(Mg + Fe)], relict Cr-spinel has high Cr# [molar Cr/(Cr + Al)] and low TiO2, and relict olivine has high Mg# and NiO content. The Cr-spinel relics are also found in the listvenites; those in serpentinite and carbonate listvenites have significantly higher Mg# than those in silica-carbonate and birbirite, suggesting re-equilibration of Cr-spinel in the later phases of listvenitization. The varieties of listvenite capture successive stages of fluid-mediated replacement reactions. The carbonate listvenite appears to have developed syn-contemporaneously with serpentinization, whereas silica-carbonate listvenite and birbirite formed later. The listvenite formation resulted in leaching and removal of some components accompanied by deposition of others in the solid products, notably CO3, SiO2, REE (especially Eu), Au, Zn, As, Sb and K. Our data show that listvenitization concentrated gold at sub-economic to economic grades; measured gold concentrations in the host serpentinite are 0.5–1.7 ng/g, versus 4–2569 ng/g in carbonate listvenite, 43–3117 ng/g in silica-carbonate listvenite and 5–281 ng/g in birbirite. The listvenite deposits in the Jabal Ess area merit further exploration for gold. [Display omitted] •The mantle section of Ess ophiolite is altered along shear zones to listvenites.•Protoliths of the of Ess ophiolitic ultramafics were formed in a fore-arc setting.•Ess listvenites are distinguished into carbonate, silica-carbonate and silica listvenites.•The listvenites capture succe