A fluorine and chlorine substituted 2D lead bromide perovskite with high phase transition temperature

Two-dimensional (2D) organic-inorganic hybrid perovskite (OIHP) has the advantages of excellent material stability, structural diversity and ease of manufacturability. It is worth noting that the fluorination strategy has been recognized as a convenient molecular design method that can effectively customize and optimize physical and chemical properties in 2D OIHP materials. However, selection the fluorine-chlorine double substituted organic amine to construct lead halide OIHP molecules was not reported. Here, for the first time, we successfully obtained a 2D metal halide perovskite compound [4-Cl-2-FBA]2PbBr4 (1) by reactions of lead bromide with two equivalents of 4-chloro-2-fluorobenzylamine [4-Cl-2-FBA] in concentrated HBr aqueous solution. Its crystal structure and purity were confirmed by X-ray single crystal diffraction and powder X-ray diffraction (PXRD). Differential scanning calorimetry (DSC) and dielectric measurement analyses showed the phase transition (PT) temperature of 1 is 380.1 ​K which is higher than that of [2-FBA]2PbBr4, (2-FBA ​= ​2-fluorobenzylammonium, 364 ​K), but lower than those of (benzylammonium)2PbBr4 (405 ​K) and [PFBA]2PbBr4 (PFBA ​= ​perfluorobenzylammonium, 440 ​K). A two-dimensional (2D) organic-inorganic hybrid perovskite material [4-Cl-2-FBA]2PbBr4 (1) with high phase transition temperature and semiconductive property was isolated by reactions of lead bromide with two equivalents of 4-chloro-2-fluorobenzylamine [4-Cl-2-FBA] in concentrated HBr aqueous solution. [Display omitted] •A fluorine and chlorine substituted 2D metal halide perovskite was firstly prepared by reactions of PbBr2 ​with 4-chloro-2-fluorobenzylamine.•DSC analysis showed the phase transition temperature of ​1 ​is 380.1 K which is higher than that of [2-FBA]2PbBr4 ​at 364 K.•The 2D metal halide perovskite was characterized by the variable temperature X-ray single crystal diffraction.