Upgraded photosensitivity under the influence of Yb doped on V2O5 thin films as an interfacial layer in MIS type Schottky barrier diode as photodiode application

In this study, rare earth ytterbium (Yb)-doped V2O5 thin films were effectively coated on glass and Si substrates by the sol-gel method combined with the spin coating method. The films' structural, morphological, optical, and electrical properties were investigated through XRD, FESEM, UV-Vis, a...

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Veröffentlicht in:Journal of solid state chemistry 2021-09, Vol.301, p.122289, Article 122289
Hauptverfasser: Balasubramani, V., Chandrasekaran, J., Manikandan, V., Le, Top Khac, Marnadu, R., Vivek, P.
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Sprache:eng
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Zusammenfassung:In this study, rare earth ytterbium (Yb)-doped V2O5 thin films were effectively coated on glass and Si substrates by the sol-gel method combined with the spin coating method. The films' structural, morphological, optical, and electrical properties were investigated through XRD, FESEM, UV-Vis, and I-V electrical conductivity. Doping on V2O5 with low Yb content of 2, 4, and 6 ​wt % have highly affected the lattice, which is shown in tetragonal and orthorhombic structures. Morphological studies show nanorods like structured. The coated thin films yield bandgap of 3.23–3.31 ​eV. The electrical properties of Cu/Yb@V2O5/n-Si type Schottky barrier diode were studied, and calculated photodiode parameters like photosensitivity, photo-responsivity, external quantum efficiency, and detectivity. Predominantly, high photosensitivity of 5545.70% is obtained for the diode with 2 ​wt % Yb@V2O5. [Display omitted] •Cu/Yb@V2O5/n-Si structured diodes are successfully fabricated.•Development of Yb@V2O5 led to an increase of barrier height.•Optimum barrier height of 0.93 ​eV is obtained owing to Yb.•Yb@V2O5 interface layer drawn high quantum efficiency of 37.90%.•Remarkably, 2 ​wt% Yb@V2O5 is obtained high photosensitivity of 5545.70 %.
ISSN:0022-4596
1095-726X
DOI:10.1016/j.jssc.2021.122289