Optimal N–Co–N bite angle for enhancing the magnetic anisotropy of zero-field Co(II) single-ion magnets in tetrahedral [N4] coordination environment

By modulating the substitution on the oxamide ligand, a mononuclear tetrahedral Co(II) complex (HNEt3)2[CoL2] (1) (H2L = N,N′-bis(methanesulfonyl)oxamide) with subtle variation in the CoN4 coordination environment was successfully synthesized, which displays zero-field slow magnetic relaxation and a...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of solid state chemistry 2021-07, Vol.299, p.122209, Article 122209
Hauptverfasser: Wang, Miao, Xu, Hong−Juan, Sun, Tong−Ming, Cui, Hui−Hui, Zhang, Yi-Quan, Chen, Lei, Tang, Yan−Feng
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:By modulating the substitution on the oxamide ligand, a mononuclear tetrahedral Co(II) complex (HNEt3)2[CoL2] (1) (H2L = N,N′-bis(methanesulfonyl)oxamide) with subtle variation in the CoN4 coordination environment was successfully synthesized, which displays zero-field slow magnetic relaxation and a hysteresis loop at 1.8 ​K. The complex adopts distorted tetrahedral coordination geometries with acute N–Co–N bite angle imposed by two mutually perpendicular oxamide ligands. Magnetic studies and computational results reveal that the acute N–Co–N bite angle seems to govern the overall magnetic anisotropy of tetrahedral Co(II) complexes with two bidentate chelated ligands containing N4-donor set. Upon reducing the bite angle, the D parameter increases gradually and reaches the maximum at about 81°, and then show a significant decrease as the angle continuing to decline. This research demonstrates that the easy-axial magnetic anisotropy can be maximized by reducing the bite angle to a certain extent, which is also feasible for tetrahedral cases with other donor sets. Magnetic studies and theoretical calculations indicate the D value of tetrahedral Co(II) complexes can be increased by appropriately reducing the bite angle of N-Co-N. [Display omitted] •A tetrahedral Co(II) complex with CoN4 coordination environment was successfully synthesized.•The complex displays zero-field slow magnetic relaxation and a hysteresis loop at 1.8 K.•Magnetic and computational studies reveal that the N-Co-N bite angle seems to govern the overall magnetic anisotropy.•The D value of tetrahedral Co(II) complexes can be maximized by reducing the N-Co-N bite angle to a certain extent.
ISSN:0022-4596
1095-726X
DOI:10.1016/j.jssc.2021.122209