Investigation of optical, structural, and antifungal properties of lindgrenite obtained by conventional coprecipitation and ultrasound-assisted coprecipitation methods

In this work, lindgrenite [Cu3(MoO4)2(OH)2] microstructures were obtained by the coprecipitation and ultrasound-assisted coprecipitation methods at different irradiation times, 10, 20, and 30 ​min. According to Raman’s active modes and infrared spectroscopies, the X-ray diffraction patterns confirme...

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Veröffentlicht in:Journal of solid state chemistry 2021-03, Vol.295, p.121957, Article 121957
Hauptverfasser: Feitosa de Carvalho, Talles André, Nobre, Francisco Xavier, de Lima Barros, Amanda, Ghosh, Anupama, de Almeida Lima e Silva, André, Oliveira dos Santos Fontenelle, Raquel, Rita de Morais Chaves Santos, Maria, Elias de Matos, José Milton
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Sprache:eng
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Zusammenfassung:In this work, lindgrenite [Cu3(MoO4)2(OH)2] microstructures were obtained by the coprecipitation and ultrasound-assisted coprecipitation methods at different irradiation times, 10, 20, and 30 ​min. According to Raman’s active modes and infrared spectroscopies, the X-ray diffraction patterns confirmed the synthesized samples’ monoclinic structure. The optical band gap (Egap) values of the samples varied from 2.3 to 2.5 ​eV, whereas the photoluminescence (PL) spectra showed some differences. Moreover, lindgrenite is thermally stable up to 270 ​°C, as seen in the thermogravimetric study. These materials were submitted to an antifungal property study. All samples’ fungal properties were evaluated against Candida albicans strain, where the Minimum Inhibitory Concentration (MIC) values were 25.6–52.6 times higher than the Amphotericin B positive control. While against Trichophyton rubrum strain, the MIC values were 3.2–105.26 times higher than the Ketoconazole positive control. The Minimum Fungal Concentration (MFC) values for C. albicans and T. rubrum were 0.039–0.078 ​μgmL−1 and 0.039–1.25 ​μgmL−1, respectively. Therefore, these results suggest that all prepared lindgrenite are promissory material in the fungal control of C. albicans and T. rubrum. The direct interaction of microorganisms with the surface of lindgrenite microcrystals results in the inactivation of the vital functions due to cell lysis. [Display omitted] •Fungal pathogens are the main causes for the loss of most crops and many others diseases.•Currently, the search of new compounds with antifungal activity is essential.•Lindgrenite [Cu3(MoO4)2(OH)2] was obtained from the regular coprecipitation and ultrasound-assisted coprecipitation method.•Lindgrenite samples were evaluated for the antifungal activity against the fungi Candida albicans and Trichophyton rubrum.
ISSN:0022-4596
1095-726X
DOI:10.1016/j.jssc.2021.121957