Non-flammable electrolyte for large-scale Ni-rich Li-ion batteries: Reducing thermal runaway risks

We present a novel, non-flammable electrolyte for Ni-rich 18650 cylindrical lithium-ion batteries (LIBs) based on a blend of triethyl phosphate (TEP) and fluorinated ethylene carbonate (FEC). We conducted a comprehensive analysis of the electrolyte, including electrochemical tests, safety evaluations, electrode surface characterizations, and quantum calculations, to elucidate its property-function relationship. We found that combining TEP with a concentrated FEC as a co-solvent (1.2 M LiPF6 in TEP/FEC, 30/70 %v) resulted in a robust solid electrolyte interface (SEI) predominantly composed of lithium fluoride (LiF). This innovation improved the SEI's stability and suppressed electrolyte decomposition during extended cycling, leading to consistent battery performance. Our findings introduce a promising non-flammable electrolyte solution for LIBs that offers both thermal runaway prevention and seamless integration into existing battery manufacturing processes. This positions it as a potential alternative to solid-state electrolytes in advanced battery technology, with the potential to revolutionize the field. •Novel Electrolyte: Non-flammable blend for 18650 LIBs using TEP and FEC.•Rigorous Analysis: Comprehensive tests and calculations for electrolyte understanding.•Enhanced SEI: TEP and FEC create a stable, lithium fluoride SEI.•Consistent Performance: Approach reduces decomposition, ensuring prolonged battery life.•Future Applications: Solution integrates with existing processes, challenging solid-state alternatives.