MOF derived ZnSe–FeSe2/RGO Nanocomposites with enhanced sodium/potassium storage

ZnSe–FeSe2/reduced graphene oxide (RGO) composites are synthesized through a rational strategy using Fe/Zn-MOF-5 as a template. Compared with the ZnSe/RGO or FeSe2/RGO composites, the ZnSe–FeSe2/RGO anode electrode exhibits a higher reversible capacity (439 mAh g−1 after 100 cycles at 100 mA g−1) fo...

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Veröffentlicht in:Journal of power sources 2020-04, Vol.455, p.227937, Article 227937
Hauptverfasser: Yuan, Jujun, Liu, Wen, Zhang, Xianke, Zhang, Yaohui, Yang, Wentao, Lai, Weidong, Li, Xiaokang, Zhang, Jiujun, Li, Xifei
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Sprache:eng
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Zusammenfassung:ZnSe–FeSe2/reduced graphene oxide (RGO) composites are synthesized through a rational strategy using Fe/Zn-MOF-5 as a template. Compared with the ZnSe/RGO or FeSe2/RGO composites, the ZnSe–FeSe2/RGO anode electrode exhibits a higher reversible capacity (439 mAh g−1 after 100 cycles at 100 mA g−1) for sodium ion batteries (SIBs). The excellent electrochemical performance of ZnSe–FeSe2/RGO composites can be attributed to the synergistic effects of the unique architecture, where ZnSe is responsible for providing a high capacity, FeSe2 improves the electrochemical stability, and RGO is beneficial for enhancing the charge transfer behavior. Furthermore, the ZnSe–FeSe2/RGO anode reveals stable reversible capacity (363 mAh g−1 after 100 cycles at 50 mA g−1) for potassium ion batteries (KIBs).
ISSN:0378-7753
1873-2755
DOI:10.1016/j.jpowsour.2020.227937