Probing structural disorder in zircon by electron backscatter diffraction (EBSD): Radiation damage and Kikuchi pattern

Electron backscatter diffraction (EBSD) was employed to probe the structural order of a zoned radiation-damaged zircon (ZrSiO4) on the sub-micron scale. The amorphous fraction of the growth-zones is in the range of ∼45–80%, due to variations in the amount of incorporated uranium and thorium (∼0.22–0...

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Veröffentlicht in:Journal of nuclear materials 2023-08, Vol.581, p.154440, Article 154440
Hauptverfasser: Beirau, Tobias, Kilian, Rüdiger, Stipp, Michael, Ewing, Rodney C.
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Sprache:eng
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Zusammenfassung:Electron backscatter diffraction (EBSD) was employed to probe the structural order of a zoned radiation-damaged zircon (ZrSiO4) on the sub-micron scale. The amorphous fraction of the growth-zones is in the range of ∼45–80%, due to variations in the amount of incorporated uranium and thorium (∼0.22–0.43 wt% UO2 and ∼0.02–0.08 wt% ThO2) and the resulting alpha-decay events over time. The obtained Kikuchi patterns’ band contrast (bc) and band slope (bs) are indicative of the degree of atomic-scale order. The excellent correlation of both parameters with the evolution of the elastic modulus validates the methods reliability.
ISSN:0022-3115
1873-4820
DOI:10.1016/j.jnucmat.2023.154440