A novel Sn/SnOx Ti3C2Tx nanosheet for adsorptive strontium removal in aqueous solution

•Sn/SnOx@Ti3C2Tx nanocomposites were synthesized using a modified hydrothermal method.•The synthesized Sn/SnOx@Ti3C2Tx efficiently removed Sr2+ in aqueous solution.•The Langmuir isotherm gave the best fit to the experimental adsorption data.•Surface complexation was the primary mechanism for Sr2+ ad...

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Veröffentlicht in:Journal of nuclear materials 2023-04, Vol.577, p.154323, Article 154323
Hauptverfasser: Ayub, Ammara, Maile, Nagesh C., Kim, Bolam, Lim, Youngsu, Ghani, Ahsan Abdul, Hussain, Muzammil, Devarayapalli, Kamakshaiah C., Kim, Gyuhyeon, Kang, Myunggoo, Ha, Jaechul, Cho, Chun-Hyung, Lee, Dae Sung
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Sprache:eng
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Zusammenfassung:•Sn/SnOx@Ti3C2Tx nanocomposites were synthesized using a modified hydrothermal method.•The synthesized Sn/SnOx@Ti3C2Tx efficiently removed Sr2+ in aqueous solution.•The Langmuir isotherm gave the best fit to the experimental adsorption data.•Surface complexation was the primary mechanism for Sr2+ adsorption onto Sn/SnOx@Ti3C2Tx. A novel Sn/SnOx@Ti3C2Tx adsorbent was fabricated via in situ growth of Sn/SnOx particles on layers of Ti3C2Tx nanosheets using facile electrostatic attraction followed by liquid-phase reduction. The characterization results demonstrated that Sn/SnOx particles were uniformly anchored onto the Ti3C2Tx surface and a sandwich-like-structured nanocomposite was formed. The introduction of Sn/SnOx particles increased the space between the Ti3C2Tx nanosheets, thereby increasing the number of active sites for Sr2+ ion removal. Moreover, the incorporated particles served as pillars to strengthen the structural stability of the Ti3C2Tx matrix and inhibited nanolayer restacking during Sr2+ion removal. Experimental results indicated that an initial strontium concentration of 5.0 mg/L was reduced to approximately 0.26 mg/L by Sn/SnOx@Ti3C2Tx within 90 min at pH 7. Furthermore, the Langmuir isotherm best fitted the adsorption data, and the maximum adsorption capacity of Sn/SnOx@Ti3C2Tx for Sr2+ ions was 71.04 mg/g at 298 K. Thus, Sn/SnOx@Ti3C2Tx nanocomposites is a promising adsorbent for the removal of Sr2+ ions from aqueous media. [Display omitted]
ISSN:0022-3115
1873-4820
DOI:10.1016/j.jnucmat.2023.154323