Critical assessment of the alleged failure of the Classical Nucleation Theory at low temperatures

•We collected published nucleation and viscosity data for 6 different glass batches.•Each glass batch was analyzed separately, following a “clean” methodology.•New steady-state nucleation test proposed.•We found only weak evidence for the alleged nucleation “break”. The Classical Nucleation Theory allegedly fails to describe the temperature dependence of the homogeneous crystal nucleation rates below the temperature of maximum nucleation, Tmax. Possible explanations for this suspected breakdown have been advanced in the literature. However, the simplest hypothesis has never been tested, that it is a byproduct of nucleation datasets that have not reached the steady-state regime. In this work, we tested this possibility by analyzing published nucleation data for oxide supercooled liquids, using only nucleation and viscosity data measured in samples of the same glass batch that also have satisfied a steady-state regime test. Furthermore, all the uncertainty and regression confidence bands were computed and considered. Having this rigorous protocol, among the 6 datasets analyzed, we only found weak evidence supporting the existence of the nucleation break in 2 datasets. Our collective results thus indicate that the break at Tmax is not a common feature of all glass-formers.