Metal-chloroglynate ionic liquids: Catalytic application for friedel-crafts [F–C] reactions

Metal-chloroglynate ionic liquids: Catalytic application for friedel-crafts [F–C] reactions

Various metal-containing ionic liquids were used as catalysts for Friedel-Crafts reactions. The reaction of R-X with benzene in the presence of M-IL (M ​= ​Fe, Zn, Cd, Cu) along with 1-glycyl-3-methylimidazolium chloride ([Gmim] Cl) ionic liquid, leads to the development of several key intermediates...

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Veröffentlicht in:Journal of the Indian Chemical Society 2021-06, Vol.98 (6), p.100081, Article 100081
Hauptverfasser: Shanmugapriya, Ramasamy, Uthayanila, Selvarasu, Ganesh, Gopalsamy Selvaraj, Karthikeyan, Parasuraman
Format: Artikel
Sprache:eng
Schlagworte:
Amino acid
C–C bond formation
Green chemistry
Ionic liquid
Metal complex
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Zusammenfassung:Various metal-containing ionic liquids were used as catalysts for Friedel-Crafts reactions. The reaction of R-X with benzene in the presence of M-IL (M ​= ​Fe, Zn, Cd, Cu) along with 1-glycyl-3-methylimidazolium chloride ([Gmim] Cl) ionic liquid, leads to the development of several key intermediates. Among them, metal-iron showed higher catalytic activity without organic solvents. This technique features high yield, a simple product isolation, ILs reusability and reduced waste discharge, thus rendering this catalytic system both effective and natural friendly. [Display omitted]
ISSN:0019-4522
DOI:10.1016/j.jics.2021.100081