Effects of green synthesis, magnetization, and regeneration on ciprofloxacin removal by bimetallic nZVI/Cu composites and insights of degradation mechanism

Schematic model for removing CIP by GT-nZVI/Cu bimetallic particles under oxic conditions [Display omitted] •Compare the reactivity of nZVI/Cu and GT-nZVI/Cu composites.•Explore the influence of initial concentration, initial pH, temperature and magnetic flux intensity on the reactivity of GT-nZVI/Cu towards CIP.•Identify the remanence effect of the material.•Identify the degradation process of CIP by the mass spectrometry (MS). In this study, nanoscale zerovalent iron (nZVI) with copper (Cu) bimetallic particles, whichare applied for degradation of Ciprofloxacin (CIP) under weak magnetic field (WMF), were synthesized using green tea extracts (GT-nZVI/Cu). The surface morphology and physicochemical properties of the novel catalytic materials were characterized. It was found that GT-nZVI was more stable and performed better in oxidation resistance than the nZVI synthesized by traditional chemical methods. Besides, the catalytic reactivity of GT-nZVI/Cu was measured with and without WMF, it is obvious from the experimental results the performance of GT-nZVI/Cu system was enhanced significantly with WMF. Moreover, WMF still had a certain effect even after being removed, which is called remanence effect. The mass spectrometry (MS) was utilized to analyze the degradation products of CIP, and the contribution of adsorption and Fenton/Fenton-like oxidation of GT-nZVI/Cu during CIP removal process was further evaluated. It was found that as the removal process progressed, the contribution ratio of Fenton/Fenton-like oxidation rose rapidly and exceeded adsorption after 20 min. Eventually, attempts have been made to regenerate GT-nZVI/Cu, in which physical recovery (ultrasonic) was the main route, and the CIP removal rate decreased as the regeneration times increased. This research provides new insights into the green synthesis and regeneration of nZVI and is expected to realize the practical application of nZVI.