Sulfide solid electrolyte thin film with high ionic conductive from slurry-casting strategy for all-solid-state lithium batteries

[Display omitted] •An ultrathin thin sulfide SSEfilm (90 μm) is synthetized by slurry-casting method.•The sulfide SSEfilm (90 μm) has high ion conductivity (1.09 × 10−3 S cm−1).•All solid-state batteries show superior electrochemical performance.•The cellulose membrane ion-conductive framework has good chemical compatibility. Sulfide solid-state electrolyte (SSE) in all-solid-state lithium batteries (ASSLBs) has attracted increasing attention due to its outstanding safety and high energy density. Nevertheless, the two main challenges of sulfide-based electrolyte are how to reduce the thickness of its film and improve its interfacial stability. In this work, Li6PS5Cl is used as a solid electrolyte, cellulose membrane as a self-limiting skeleton, heptane as a dispersant and SEBS as a binder, and a 90 μm ultrathin sulfide electrolyte film is prepared by using the free-standing slurry casting strategy. The ionic conductivity of sulfide SSE film is 1.09 × 10−3 S cm−1 at room temperature. Furthermore, the ASSLBs with cathode (LiNbO3@LiNi0.6CO0.2Mn0.2O2) and anode materials (lithium-indium alloy) are prepared. The discharge capacity of the button cells assemble with sulfide solid electrolyte film is 161.2 mAh/g after 150 cycles with a capacity retention of 87 % under 0.1 C at 25 °C. This study provides ultrahigh ionic conductivity sulfide-based electrolyte film design principle towards promising possible strategies for ASSLBs.