Evaluation of the elemental distribution in soil samples collected from ship-breaking areas and an adjacent island

•Using INAA, elemental abundances of soil samples from ship-breaking yards and an adjacent island were determined.•Heavy minerals from similar geochemical settings were also analyzed for elemental composition by INAA.•Environmental indices, inter-element correlation study and PCA were performed to e...

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Veröffentlicht in:Journal of environmental chemical engineering 2019-06, Vol.7 (3), p.103189, Article 103189
Hauptverfasser: Khan, Rahat, Das, Sopan, Kabir, Shaiful, Habib, Md. Ahosan, Naher, Kamrun, Islam, Mohammad Amirul, Tamim, Umma, Rahman, A.K.M. Rezaur, Deb, Arun Kumar, Hossain, Syed Mohammod
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Sprache:eng
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Zusammenfassung:•Using INAA, elemental abundances of soil samples from ship-breaking yards and an adjacent island were determined.•Heavy minerals from similar geochemical settings were also analyzed for elemental composition by INAA.•Environmental indices, inter-element correlation study and PCA were performed to evaluate the elemental distribution.•Elemental enrichments in ship-breaking yards are higher than UCC while Sandwip island possesses crustal origin.•Acknowledging the anthropogenic input, heavy mineral’s distribution is also accountable for elemental distribution. Ship-breaking yards in the world mostly reside along the coastal areas which possess diverse elemental contents due to the presence of heavy minerals. So to explain the heavy elemental enrichment of ship-breaking sites in terms of only anthropogenic contribution is insufficient. While studying elemental distribution of ship-breaking sites, choosing appropriate control sample is vital. To evaluate the elemental distribution in ship-breaking yards of Bangladesh and in an adjacent island (Sandwip), soil samples from each site and some heavy minerals have been analyzed for Na, K, Sc, Cr, Fe, Co, As, Sb, Cs, La, Ce, Sm, Hf and Th abundances by neutron activation analysis. For assessing elemental distribution, pollution load index (PLI), geo-accumulation index and inter-element correlation study were performed. Co-related variation of Cr and Fe (r = 0.651) and chemical compositions of heavy minerals invoke that a significant portion of elemental enrichment in ship-breaking yards seems to have mineralogical origin while the enrichments of As, Sb and Cs (mean abundances: 11.3 ± 3.9, 5.66 ± 4.97 and 10.9 ± 6.6 ppm, respectively) are solely originated from anthropogenic activities (e.g., ship-breaking). On the other hand, elemental distribution of Sandwip (which is sometimes used as control sample) seems to be unaffected by the mainland ship-breaking activities and possesses crustal origin, though a minute fractionation of heavy metals is observed within the east (PLI: 0.84 ± 0.05) and west (PLI: 0.52 ± 0.04) side of the island. For the first time, this study reveals the mineralogical contribution of heavy elements in ship-breaking site and will be decisive for choosing proper elemental abundances of control site.
ISSN:2213-3437
2213-3437
DOI:10.1016/j.jece.2019.103189